Digging gold: keV He+ ion interaction with Au
نویسندگان
چکیده
Helium ion microscopy (HIM) was used to investigate the interaction of a focused He(+) ion beam with energies of several tens of kiloelectronvolts with metals. HIM is usually applied for the visualization of materials with extreme surface sensitivity and resolution. However, the use of high ion fluences can lead to significant sample modifications. We have characterized the changes caused by a focused He(+) ion beam at normal incidence to the Au{111} surface as a function of ion fluence and energy. Under the influence of the beam a periodic surface nanopattern develops. The periodicity of the pattern shows a power-law dependence on the ion fluence. Simultaneously, helium implantation occurs. Depending on the fluence and primary energy, porous nanostructures or large blisters form on the sample surface. The growth of the helium bubbles responsible for this effect is discussed.
منابع مشابه
Analysis of native biological surfaces using a 100 kV massive gold cluster source.
In the present work, the advantages of a new, 100 kV platform equipped with a massive gold cluster source for the analysis of native biological surfaces are shown. Inspection of the molecular ion emission as a function of projectile size demonstrates a secondary ion yield increase of ~100× for 520 keV Au(400)(4+) as compared to 130 keV Au(3)(1+) and 43 keV C(60). In particular, yields of tens o...
متن کاملIn situ TEM ion irradiation and implantation effects on Au nanoparticle morphologies.
Energetic heavy and light ion effects on gold nanoparticles were probed by irradiating 20 and 60 nm diameter nanoparticles with either 3 MeV Cu(3+) or 10 keV He(+) ions in situ inside of a transmission electron microscope. Both ion species caused sintering, agglomeration, and ablation of the nanoparticles via sputtering, although at different rates.
متن کاملIrradiation of olivine by 4 keV He: Simulation of space weathering by the solar wind
[1] We have studied the effects of 4 keV He ion irradiation on olivine while measuring, in situ, changes in the near-infrared (NIR) reflectance and in the chemical composition of the surface. The observed changes in reflectance are reddening and the attenuation of the Fe-3d absorption bands in the NIR. Spectral reddening of irradiated olivine powder (<45 mm) correlates with the amount of metall...
متن کاملGold ion implantation into alumina using an "inverted ion source" configuration.
We describe an approach to ion implantation in which the plasma and its electronics are held at ground potential and the ion beam is injected into a space held at high negative potential, allowing considerable savings both economically and technologically. We used an "inverted ion implanter" of this kind to carry out implantation of gold into alumina, with Au ion energy 40 keV and dose (3-9) × ...
متن کاملGold ion-angiotensin peptide interaction by mass spectrometry.
Stimulated by the interest in developing gold compounds for treating cancer, gold ion-angiotensin peptide interactions are investigated by mass spectrometry. Under the experimental conditions used, the majority of gold ion-angiotensin peptide complexes contain gold in the oxidation states I and III. Both ESI-MS and MALDI-TOF MS detect singly/multiply charged ions for mononuclear/multinuclear go...
متن کامل